Experimental evidence for large ring metallacycle intermediates in polyethylene chain growth using homogeneous chromium catalysts AK Tomov, JJ Chirinos, DJ Jones, RJ Long, VC Gibson Journal of the American Chemical Society 127 (29), 10166-10167, 2005 | 190 | 2005 |
Catalytic polymerization of ethylene in emulsion R Soula, C Novat, A Tomov, R Spitz, J Claverie, X Drujon, J Malinge, ... Macromolecules 34 (7), 2022-2026, 2001 | 174 | 2001 |
Mono-versus bis-chelate formation in triazenide and amidinate complexes of magnesium and zinc N Nimitsiriwat, VC Gibson, EL Marshall, P Takolpuckdee, AK Tomov, ... Inorganic chemistry 46 (23), 9988-9997, 2007 | 125 | 2007 |
Distinguishing Chain Growth Mechanisms in Metal-catalyzed Olefin Oligomerization and Polymerization Systems: C2H4/C2D4 Co-oligomerization … AK Tomov, VC Gibson, GJP Britovsek, RJ Long, M van Meurs, DJ Jones, ... Organometallics 28 (24), 7033-7040, 2009 | 122 | 2009 |
Very active neutral P, O-chelated nickel catalysts for ethylene polymerization R Soula, JP Broyer, MF Llauro, A Tomov, R Spitz, J Claverie, X Drujon, ... Macromolecules 34 (8), 2438-2442, 2001 | 122 | 2001 |
Emulsion polymerization of ethylene in water medium catalysed by organotransition metal complexes A Tomov, JP Broyer, R Spitz Macromolecular Symposia 150, 53-58, 2000 | 115 | 2000 |
An unprecedented α-olefin distribution arising from a homogeneous ethylene oligomerization catalyst AK Tomov, JJ Chirinos, RJ Long, VC Gibson, MRJ Elsegood Journal of the American Chemical Society 128 (24), 7704-7705, 2006 | 110 | 2006 |
The effect of the central donor in bis (benzimidazole)-based cobalt catalysts for the selective cis-1, 4-polymerisation of butadiene R Cariou, JJ Chirinos, VC Gibson, G Jacobsen, AK Tomov, GJP Britovsek, ... Dalton Transactions 39 (38), 9039-9045, 2010 | 98 | 2010 |
Ethylene oligomerization beyond Schulz–Flory distributions GJP Britovsek, R Malinowski, DS McGuinness, JD Nobbs, AK Tomov, ... ACS Catalysis 5 (11), 6922-6925, 2015 | 90 | 2015 |
The effect of imine-carbon substituents in bis (imino) pyridine-based ethylene polymerisation catalysts across the transition series TM Smit, AK Tomov, GJP Britovsek, VC Gibson, AJP White, DJ Williams Catalysis Science & Technology 2 (3), 643-655, 2012 | 74 | 2012 |
1, 3-Butadiene polymerization by bis (benzimidazolyl) amine metal complexes: remarkable microstructural control and a protocol for in-reactor blending of trans-1, 4-, cis-1, 4 … R Cariou, J Chirinos, VC Gibson, G Jacobsen, AK Tomov, MRJ Elsegood Macromolecules 42 (5), 1443-1444, 2009 | 69 | 2009 |
Thio-Pybox and Thio-Phebox complexes of chromium, iron, cobalt and nickel and their application in ethylene and butadiene polymerisation catalysis JD Nobbs, AK Tomov, R Cariou, VC Gibson, AJP White, GJP Britovsek Dalton Transactions 41 (19), 5949-5964, 2012 | 64 | 2012 |
Ethene polymerization by binuclear nickel—ylide complexes K Kurtev, A Tomov Journal of molecular catalysis 88 (2), 141-150, 1994 | 63 | 1994 |
Dramatic effect of heteroatom backbone substituents on the ethylene polymerization behavior of bis (imino) pyridine iron catalysts TM Smit, AK Tomov, VC Gibson, AJP White, DJ Williams Inorganic chemistry 43 (21), 6511-6512, 2004 | 58 | 2004 |
Binuclear nickel-ylide complexes as effective ethylene oligomerization/polymerization catalysts A Tomov, K Kurtev Journal of Molecular Catalysis A: Chemical 103 (2), 95-103, 1995 | 56 | 1995 |
Group 4 metal complexes bearing new tridentate (NNO) ligands: Benzyl migration and formation of unusual C–C coupled products R Cariou, VC Gibson, AK Tomov, AJP White Journal of Organometallic Chemistry 694 (5), 703-716, 2009 | 46 | 2009 |
Functionalised polyolefin synthesis using [P, O] Ni catalysts VC Gibson, A Tomov Chemical Communications, 1964-1965, 2001 | 43 | 2001 |
The effect of bulky substituents on the olefin polymerisation behaviour of nickel catalysts bearing [P, O] chelate ligands VC Gibson, A Tomov, AJP White, DJ Williams Chemical Communications, 719-720, 2001 | 39 | 2001 |
Mechanistic study of ethylene tri-and tetramerisation with Cr/PNP catalysts: effects of additional donors GJP Britovsek, DS McGuinness, AK Tomov Catalysis Science & Technology 6 (23), 8234-8241, 2016 | 38 | 2016 |
Ethylene polymerisation by a copper catalyst bearing α-diimine ligands VC Gibson, A Tomov, DF Wass, AJP White, DJ Williams Journal of the Chemical Society, Dalton Transactions, 2261-2262, 2002 | 35 | 2002 |